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41.
Noreen Joyce Evans D. Conrad Gregoire Wayne D. Goodfellow Norman Miles Jn Veizer 《Meteoritics & planetary science》1994,29(2):223-235
Abstract— Grain size separates of the Cretaceous-Tertiary (K-T) fireball layer at marine sites and the entire K-T boundary interval at nonmarine sites (fireball layer, ejecta layer, coal seam) were analysed for platinum-group elements (PGE: Ru, Ir, Ft, Pd, Rh) and Au using inductively coupled plasma mass-spectrometry. X-ray diffractometry and scanning electron microscopy were performed on each fraction to establish the mineralogy. It was determined that the most abundant minerals in the finest fraction were a smectite-group mineral at marine K-T sites and illite-smectite mixed layer clay at nonmarine K-T sites. Positive correlation of PGE content and mineralogy indicates that the PGE are presently associated with these clay minerals which were likely formed by alteration of a condensed mafic phase (e.g., olivine or pyroxene). The correlation of clay mineral abundance with PGE content is imperfect because not all of the clay minerals in the fireball layer are derived by alteration of the original condensed ejecta. In addition, undetected PGE host(s), present in trace amounts, are likely also present. 相似文献
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Manel Prada Franois Lavou Muhammad Mudasar Saqab Brian M. O'Reilly Sergei Lebedev John J. Walsh Conrad Childs 《Basin Research》2019,31(1):59-76
The Porcupine Basin is a Mesozoic failed rift located in the North Atlantic margin, SW of Ireland, in which a postrift phase of extensional faulting and reactivation of synrift faults occurred during the Mid–Late Eocene. Fault zones are known to act as either conduits or barriers for fluid flow and to contribute to overpressure. Yet, little is known about the distribution of fluids and their relation to the tectono‐stratigraphic architecture of the Porcupine Basin. One way to tackle this aspect is by assessing seismic (Vp) and petrophysical (e.g., porosity) properties of the basin stratigraphy. Here, we use for the first time in the Porcupine Basin 10‐km‐long‐streamer data to perform traveltime tomography of first arrivals and retrieve the 2D Vp structure of the postrift sequence along a ~130‐km‐long EW profile across the northern Porcupine Basin. A new Vp–density relationship is derived from the exploration wells tied to the seismic line to estimate density and bulk porosity of the Cenozoic postrift sequence from the tomographic result. The Vp model covers the shallowest 4 km of the basin and reveals a steeper vertical velocity gradient in the centre of the basin than in the flanks. This variation together with a relatively thick Neogene and Quaternary sediment accumulation in the centre of the basin suggests higher overburden pressure and compaction compared to the margins, implying fluid flow towards the edges of the basin driven by differential compaction. The Vp model also reveals two prominent subvertical low‐velocity bodies on the western margin of the basin. The tomographic model in combination with the time‐migrated seismic section shows that whereas the first anomaly spatially coincides with the western basin‐bounding fault, the second body occurs within the hangingwall of the fault, where no major faulting is observed. Porosity estimates suggest that this latter anomaly indicates pore overpressure of sandier Early–Mid Eocene units. Lithological well control together with fault displacement analysis suggests that the western basin‐bounding fault can act as a hydraulic barrier for fluids migrating from the centre of the basin towards its flanks, favouring fluid compartmentalization and overpressure of sandier units of its hangingwall. 相似文献
47.
Assessment of the historical trace metal contamination of sediments in the Elizabeth River, Virginia
Two sediment cores (Southern Branch, PC-1, and Western Branch, WB-2) were taken from the highly industrialized Elizabeth River, Virginia. The concentrations of trace metals cadmium, cobalt, chromium, copper, nickel, lead and zinc, major elements iron, manganese and aluminum, organic carbon content and the specific surface area of the sediments were determined in each of the cores. Down-core variations in metals varied significantly in each core with maximum contamination events occurring at different times in different portions of the river. In PC-1, maximum metal concentrations were seen after the appearance of (137)Cs. In contrast, the highest levels in WB-2 occurred well before the appearance of (137)Cs. Although stricter environmental regulations have caused a decrease in metal concentrations since the 1980s, the concentrations in the surface sediments of many trace metals were elevated to levels 2-5 times higher than the levels at the bottom of the cores in both the Southern and Western Branches of the river. 相似文献
48.
Sven Klimpel Markus Wilhelm Busch Tracey Sutton Harry Wilhelm Palm 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(4):596-603
Seven meso- and bathy-pelagic fish species from the Mid-Atlantic Ridge (MAR) were firstly studied for fish parasites and feeding ecology. With a total of seven parasite species, the 247 meso- and bathy-pelagic deep-sea fish specimens belonging to the families Melamphaidae (3 spp.), Myctophidae (3 spp.) and Stomiidae (1 sp.) revealed low parasite diversity. The genetically identified nematodes Anisakis simplex (s.s.) and Anisakis pegreffii from the body cavity, liver and muscles of Myctophum punctatum were the most abundant parasites, reaching a prevalence of 91.4% and mean intensity of 3.1 (1–14). Anisakis sp. (unidentified) infected Chauliodus sloani and Poromitra crassiceps. Bothriocephalidean and tetraphyllidean cestode larvae infected Benthosema glaciale, the latter also occurring in C. sloani and Scopelogadus beanii, at low prevalences. Adult parasites at low infection rates included the digenean Lethadena sp. (2.9%), and the two copepod species Sarcotretes scopeli (5.7%) and Tautochondria dolichoura (5.3–11.4%). The myctophid Lampanyctus macdonaldi and the melamphaid Scopelogadus mizolepis mizolepis were free of parasites. Analyses of the stomach contents revealed crustaceans, especially copepods and euphausiids for the myctophids and also amphipods for the melamphaids as predominant prey items. While all stomachs showing distinct content comprising often unidentified ‘tissue’ (possibly gelatinous zooplankton), only C. sloani preyed upon fish. Though this feeding habit would enable transfer of a variety of crustacean-transmitted parasites into the fish, the parasite fauna in the meso- and bathy-pelagic fish was species poor. All observed parasites showed low host specificity, demonstrating no distinct pattern of host–parasite co-evolution. The MAR is no barrier for the parasite distribution in the North Atlantic meso- and bathy-pelagial. 相似文献
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Conrad S. Chapman Gabriele Capodaglio Clara Turetta Constant M.G. van den Berg 《Marine environmental research》2009,67(1):17-24
Benthic fluxes of copper, copper complexing ligands and thiol compounds in the shallow waters of Venice Lagoon (Italy) were determined using benthic chambers and compared to porewater concentrations to confirm their origin. Benthic copper fluxes were small due to small concentration differences between the porewaters and the overlying water, and the equilibrium concentration was the same at both sites, suggesting that the sediments acted to buffer the copper concentration. Thiol fluxes were ~10 × greater at 50–60 pmol cm?2 h?1, at the two sites. Porewater measurements demonstrated that the sediments were an important source of the thiols to the overlying waters. The overlying waters were found to contain at least two ligands, a strong one, L1 (log K′CuL1 = 14.2) and a weaker one, L2 (log K′CuL2 = 12.5). The concentration of L1 remained relatively constant during the incubation and similar to that of copper, whereas that of L2 was in great excess of copper, its concentration balanced by porewater releases and breakdown, probably due to uptake by microorganisms, similar to that of the thiol compounds. Similarity of the thiol and L2 concentrations and similar complex stability with copper suggest that L2 was dominated by the thiols. The free copper concentration ([Cu´]) in the Lagoon waters was lowered by a factor of 105 as a result of the organic complexation. 相似文献
50.
The geology of the Last Interglaciation (sensu stricto, marine isotope substage (MIS) 5e) in the Bahamas records the nature of sea level and climate change. After a period of quasi-stability for most of the interglaciation, during which reefs grew to +2.5 m, sea level rose rapidly at the end of the period, incising notches in older limestone. After brief stillstands at +6 and perhaps +8.5 m, sea level fell with apparent speed to the MIS 5d lowstand and much cooler climatic conditions. It was during this regression from the MIS 5e highstand that the North Atlantic suffered an oceanographic “reorganization” about 118±3 ka ago. During this same interval, massive dune-building greatly enlarged the Bahama Islands. Giant waves reshaped exposed lowlands into chevron-shaped beach ridges, ran up on older coastal ridges, and also broke off and threw megaboulders onto and over 20 m-high cliffs. The oolitic rocks recording these features yield concordant whole-rock amino acid ratios across the archipelago. Whether or not the Last Interglaciation serves as an appropriate analog for our “greenhouse” world, it nonetheless reveals the intricate details of climatic transitions between warm interglaciations and near glacial conditions. 相似文献